How to Quantify the Adsorption of Cyanuric Acid on Activated Carbon Used from Swimming Pool Disinfection?

The physical and chemical characteristics of an adsorbent are key factors determining its efficiency in relation to a particular adsorbate molecule. The adsorption of cyanuric acid (cya) on activated carbon (AC) has not been extensively explored in terms of its basic phenomenon and specific surface interactions. Cya is an important molecule in the swimming pool industry, as it protects free chlorine from UV light degradation. A proper characterization of AC will be beneficial for swimming pool product suppliers to determine the criteria while purchasing it to remove excess cya accumulated in pools. A detailed investigation of the physicochemical properties of activated carbon was conducted to assess its potential to adsorb cya from water. The effect of the adsorption capacity under various pH conditions was studied and it was found that acidic pH favors the adsorption process. With the help of temperature-programmed desorption coupled with mass spectrometry (TPD-MS) and X-ray photoelectron spectroscopy (XPS), the surface chemistry was well analyzed for a proper understanding of the adsorbent-adsorbate interaction. While conventional pool test equipment gives inconsistent readings of the cya concentration, a UV-vis spectroscopy-based methodology has been developed to accurately measure traces of cya in water. This method can be helpful to validate the accuracy of pool-testers for research and development purposes. The batch adsorption experiments revealed that cya adsorption on activated carbon follows pseudo-second-order kinetics, which confirms that the adsorption mechanism is chemisorption, which in fact, depends highly on the surface chemistry of the AC and the reaction pH.

Pre- and post-pyrolysis effects on iron impregnation of ultrasound pre-treated softwood biochar for potential catalysis applications.

Slow pyrolysis is widely used to convert biomass into useable form of energy. Ultrasound pre-treatment assisted pyrolysis is a recently emerging methodology to improve the physicochemical properties of products derived. Biochar, the solid residues obtained from pyrolysis, is getting considerable attention because of its good physicochemical properties. Various modification techniques have been implemented on biochars to enhance their properties. Ultrasonic pre-treated wood biochar has showcased efficient surface and adsorption properties. Iron impregnated biochar is interesting as it has potentially proved the efficiency as an efficient low-cost catalyst. In this study, by combining the advantages of ultrasonic pre-treatment and iron impregnation, we have synthesized a series of Fe-impregnated biochar from softwood chips. Pre- and post-pyrolysis methods using a lab-scale pyrolyser had been implemented to compare the pyrolysis product yields and degree of impregnation. Biochars derived from ultrasound pre-treated woodchips by post pyrolysis demonstrated better impregnation of Fe ions on surface with better distribution of pyrolysis products such as biochar and biogas. The surface functionality of all ultrasound pre-treated biochars remained the same. However, post-pyrolysed samples at high frequency ultrasound pre-treatment showed better thermal stability. The chemical characteristics of these modified biochars are interesting and can indeed be used as a cost-effective replacement for various catalytic applications.

Enhanced activation of ultrasonic pre-treated softwood biochar for efficient heavy metal removal from water.

Physical and chemical modification on biochar is an interesting approach to enhance the properties and make them potential candidates in adsorption of heavy metals from water. Studies have shown that ultrasound treatments as well as alkali activations on biochar has positive impact on adsorption behaviour of the material. Base activation on biochar derived from ultrasound pre-treated woodchips were studied to understand the influence of ultrasound pre-treatment on chemical modification of biochar and the adsorption properties emerged from it. 40 and 170 kHz ultrasound pre-treated softwood woodchips were subjected to laboratory scale pyrolysis and the resulted biochars were treated with NaOH. The physicochemical properties were examined, and the adsorption experiments revealed that ultrasound pre-treatment assisted biochars have better adsorption capacity as compared to untreated biochar samples after activation. 170 kHz pre-treated sample exhibited an equilibrium adsorption capacity of 19.99 mg/g which is almost 22 times higher than that of corresponding non-activated sample. The ultrasound pre-treated samples showed improved competitive adsorption behaviour towards copper ions in comparison with nickel or lead. The overall study suggests that ultrasound pre-treated biochars combined with alkali activation enhances the heavy metal removal efficiency and these engineered biochars can be used as an effective adsorbent in the field of wastewater treatment.